中国石油勘探 ›› 2012, Vol. 17 ›› Issue (2): 27-31,88.

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大宛齐原油金刚烷类化合物及其在油气运移中的应用

任康绪,黄光辉,肖中尧,张敏,张宝收,魏红兴,马志远   

  1. 中国石油塔里木油田公司勘探开发研究院;长江大学地球化学系;中石化国际石油工程公司
  • 出版日期:2012-04-15 发布日期:2012-04-15
  • 基金资助:
    国家重点基础研究发展计划(973计划)“中国西部叠合盆地深部油气复合成藏机制与富集规律”子课题“中国西部叠合盆地深部油气富集规律与勘探潜力预测”(2011CB201106)

Application of Diamondoids to Hydrocarbon Migration in Dawanqi Oilfield, Tarim Basin

Ren Kangxu,Huang Guanghui,Xiao Zhongyao,Zhang Min,Zhang Baoshou,Wei Hongxing and Ma Zhiyuan   

  1. Ren Kangxu1, Huang Guanghui2, Xiao Zhongyao1, Zhang Min2, Zhang Baoshou1, Wei Hongxing1, Ma Zhiyuan3 1. Research Institute of Exploration and Development, PetroChina Tarim Oilfield Company, Korla City, Xinjiang Uygur Autonomous Region 841000; 2. Department of Geochemistry, Yangtze University, Jinzhou City, Hubei Province 434023; 3. Sinopec International Petroleum Service Corporation, Beijing 100011
  • Online:2012-04-15 Published:2012-04-15

摘要: 大宛齐油田是一个以轻质油为主的油田。原油中生物标志化合物浓度低,中性含氮化合物丰度同样较低,这给原油运移特征的研究带来了困难。研究表明,该油田原油中普遍存在一类热稳定性极高的化合物,即金刚烷类化合物,包括金刚烷和双金刚烷类化合物。系列样品色谱分析表明,该油田不同结构的化合物,其色谱保留行为存在较大差异。利用色谱保留行为与地层色层效应在原理上的相似性,用不同结构的金刚烷类化合物的比值研究了原油运移分馏效应,结果表明该油田金刚烷类运移参数具有较好的分布规律:总体上,随油藏埋深变浅,金刚烷类运移参数增加,表明原油主要存在纵向上的运移过程;在深大断裂发育区域,存在运移参数的低值分布区;平面上,运移参数自深大断裂附近由南向北增加,这种规律提供了该油田原油存在自南向北运移的重要证据。

关键词: 塔里木盆地, 大宛齐油田, 金刚烷类化合物, 运移参数, 分馏效应

Abstract: Dawanqi Oilfield is a light oil-based oilfield. The concentration of biomarkers and the abundance of neutral nitrogenous compounds are comparatively low that make it difficult to reveal the crude oil migration characteristics. Research shows that, commonly, there is a kind of compounds with high thermal stability in oils of Dawanqi Oilfield. They are the diamondoids, including diamondoid and bidiamondoid hydrocarbons. Chromatographic analysis indicates the compounds with different structure have great discrepancy in their chromatographic retention behavior. According to the similarity of chromatographic retention behavior and stratum chromatographic effect in principle, the oil fractionation effects of Dawanqi Oilfield during migration have been studied by using the ratios of diamondoids with different chemical structure. The results show that the migration parameters based on diamondoids have obvious distribution law. In general, the migration parameters of diamondoids increase as the buried depth gets shallower. The results indicate that crude oil migrates vertically. The migration parameters of diamondoids are low in areas near deep faults. The migration parameters of diamondoid increase from south to north far from those deep faults in the plane. All these show that the main migration direction of the crude oil in Dawanqi Oilfield is from south to north.

Key words: Tarim Basin, Dawanqi Oilfield, diamondoids, migration parameter, fractionation effect

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